رزومه


وحید امانی

وحید امانی

دانشیار

رزومه
وحید امانی

دانشیار وحید امانی

Synthesis of isomorphous prototypic [CrFe<sub>2</sub>O(AcO) <sub>6</sub>(TEP)<sub>3</sub>]Cl and [CrFe<sub>2</sub>O(AcO)<sub>6</sub>(TMP) <sub>3</sub>]Cl as oxo-centered hetero tri-nuclear carboxylate complexes

نویسندگانRafizadeh M., Tayebee R., Amani V.
نشریهTurkish Journal of Chemistry
تاریخ انتشار۲۰۰۵

چکیده مقاله

[CrFe2O(AcO)6(TEP)3]Cl, (1), and [CrFe2O(AcO)6(TMP)3]Cl, (2), were prepared by replacing 3 water molecules in the [CrFe2O(AcO)6(H 2O)3]Cl complex with triethyl- and trimethyl-phosphates, respectively. FT-IR spectroscopy confirmed an oxo-centered, carboxylate-bridged, heteronuclear triangular structure for the title compounds. M3O and MO4 units adopted D3h and D4h local symmetry, respectively, and are surrounded by 6 bridging acetates with C2v local symmetry. © TÜBİTAK.

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