Synthesis, characterization, and crystal structures of a new coordination polymer of manganese(II) containing dimethyl phosphate

چکیده مقاله

The reaction of MnCl₂ with TMP (TMP = Trimethyl phosphate) in THF (THF = tetrahydroforan), led to the coordination polymer [Mn ₂(ν₃-DMP)₂(μ-DMP)₂] _n (1) (DMP = dimethyl phosphate). This complex was characterized by elemental analysis, IR spectroscopy and single-crystal structure of 1. Crystal data for 1 at -173°C: triclinic, space group P1̄, a = 9.7071(11), b = 10.4482(11), c = 10.6242(11) Å, α = 88.892(2)°, β= 80.829(2)°, γ = 87.572(2)°, Z = 2, R1 = 0.0441. © 2007 WILEY-VCH Verlag GmbH & Co. KGaA.